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AQA GCSE Chemistry

Revision Notes
(Causes of Atmospheric Pollution)

Particulates

Particulates

Definition of Particulates

Particulates are tiny solid particles suspended in the air. They include dust, soot, and smoke. These particles can be naturally occurring, such as volcanic ash or sea salt, or human-made, often produced by burning fuels or industrial activities.

Sources of Particulates

Particulates come from various sources, both natural and human-made:

  • Burning fossil fuels: When coal, oil, or petrol is burned, tiny particles of soot and ash are released into the atmosphere.
  • Vehicle exhausts: Cars, lorries, and buses emit particulates, especially diesel engines which produce fine soot particles.
  • Industrial processes: Factories and power stations release particulates during manufacturing and energy production.
  • Natural sources: Volcanic eruptions release ash, and natural dust storms also contribute particulates to the air.

For example, when coal is burned in a power station, incomplete combustion can produce soot particles that escape into the air.

Effects on Health and Environment

Particulates have several harmful effects:

  • Respiratory problems: Breathing in particulates can irritate the lungs and cause health issues such as asthma, bronchitis, and other breathing difficulties. Fine particulates can penetrate deep into the lungs and even enter the bloodstream.
  • Global dimming: Particulates reflect sunlight back into space, reducing the amount of sunlight reaching the Earth6s surface. This can lower temperatures and affect weather patterns. Global dimming can also contribute to changes in rainfall patterns and may affect climate systems.
  • Damage to ecosystems: Particulates can settle on plants and water bodies, harming wildlife and reducing photosynthesis by blocking sunlight.

For instance, in cities with high air pollution, people often suffer from increased respiratory illnesses due to the high concentration of particulates in the air.

Control and Reduction Methods

Several methods help reduce particulate pollution:

  • Filters and scrubbers in industry: Factories use filters to trap particulates before gases are released into the atmosphere. Scrubbers chemically remove particulates from exhaust gases. Scrubbers use liquids or chemicals to capture and neutralize particulates in exhaust gases.
  • Use of cleaner fuels: Switching to fuels that burn more cleanly, such as natural gas instead of coal, reduces particulate emissions.
  • Legislation and regulations: Governments set limits on particulate emissions and enforce laws to reduce pollution from vehicles and industry.

For example, many UK cities have introduced low emission zones to reduce vehicle particulates by restricting older, more polluting vehicles.

Learning example: Calculating percentage reduction in particulate emissions

A factory reduces its particulate emissions from 500 mg/m9 to 350 mg/m9 after installing filters. Calculate the percentage reduction.

Here, Initial is the initial emission value and Final is the emission value after reduction.

Percentage reduction = InitialFinalInitial×100\frac{\text{Initial} - \text{Final}}{\text{Initial}} \times 100

= 500350500×100=150500×100=30%\frac{500 - 350}{500} \times 100 = \frac{150}{500} \times 100 = 30\%

So, the filters reduce particulate emissions by 30\%.

PracticeExample 2

Worked Example

Example: A diesel vehicle emits 0.8 mg of particulates per km. After engine improvements, emissions drop to 0.5 mg per km. What is the percentage decrease?

PracticeExample 3

Worked Example

Example: A power station emits 1200 mg/m9 of particulates before installing scrubbers and 900 mg/m9 after. Calculate the percentage reduction.

PracticeExample 4

Worked Example

Example: If a city6s particulate concentration is 150 bcg/m9 and the legal limit is 100 bcg/m9, by what percentage must the particulates be reduced to meet the limit?

  • Remember that particulates are tiny solid particles, not gases like carbon dioxide or sulfur dioxide.
  • Think of global dimming as a "sunlight blocking" effect caused by particulates reflecting sunlight away.
  • When calculating percentage changes, always subtract the smaller value from the larger one and divide by the original amount.

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