Cambridge (CIE) IGCSE Chemistry
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(Atomic Structure and the Periodic Table)
Electron Configuration
Electron Configuration
Electron configuration shows how an atom’s electrons are arranged in shells around the nucleus. For the first 20 elements, we use simple shell numbers like . This helps predict reactivity and position in the Periodic Table.
Key rules (elements 1–20)
- Fill inner shells first (closest to the nucleus).
- 1st shell holds up to 2 electrons.
- 2nd shell holds up to 8 electrons.
- 3rd shell holds up to 8 electrons (for to ).
- In a neutral atom, number of electrons = proton (atomic) number.
How to write it
- Find the proton number (from the Periodic Table).
- Place electrons into shells using the 2, 8, 8 rule.
- Write as numbers separated by commas, e.g. .
Links to the Periodic Table
- Period number = number of occupied shells.
- For Groups I–VII, group number = number of outer (valence) electrons.
- Group VIII (also called Group 18) noble gases have a full outer shell and are unreactive.
Ions and stability
Atoms often gain or lose electrons to get a full outer shell. Metals usually lose electrons to form positive ions; non-metals usually gain electrons to form negative ions.
- () → : loses 1 electron →
- () → : gains 1 electron →
- () → : loses 2 electrons →
Worked Example
Worked example 1: Sodium
Question: Write the electron configuration of sodium and state its group and period. Predict the ion it forms.
Worked Example
Worked example 2: Sulfur
Question: Find the configuration of sulfur and the ion it tends to form.
Common misconceptions
- Electrons are not in the nucleus; they occupy shells around it.
- For elements 1–20, use (not ).
- Forming ions changes electrons, not protons (the proton number stays the same).
Tuity Tip
Hover me!
Remember: “2-8-8 for twenty.” Use “GPS” to navigate the table: Group = outer electrons, Period = number of occupied Shells. Noble gases are stable because their outer shell is full.
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