Cambridge (CIE) IGCSE Chemistry

Revision Notes

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(Simple Molecules and Covalent Bonds)

Covalent Bonds

Covalent Bonds

A covalent bond is a shared pair of electrons between two non‑metal atoms. By sharing, each atom reaches a stable outer shell like a noble gas (often called the octet). Hydrogen aims for 2 electrons; most others aim for 8.

Why atoms share

Think of two neighbours sharing a fence. Each uses the same fence, and both gardens are secure. In a covalent bond, the shared pair of electrons “belongs” to both atoms, helping each feel full on the outside shell.

Single, double and triple bonds

• Single bond: 1 shared pair (2 electrons). Example: H2\mathrm{H_2}, Cl2\mathrm{Cl_2}, HCl\mathrm{HCl}.
• Double bond: 2 shared pairs (4 electrons). Example: O2\mathrm{O_2}, CO2\mathrm{CO_2}.
• Triple bond: 3 shared pairs (6 electrons). Example: N2\mathrm{N_2}.

How many bonds does an atom usually form?

  • H and Cl make 1 bond
  • O makes 2 bonds
  • N makes 3 bonds
  • C makes 4 bonds

Examples: CH4\mathrm{CH_4} (carbon 4 bonds), H2O\mathrm{H_2O} (oxygen 2 bonds), NH3\mathrm{NH_3} (nitrogen 3 bonds), HCl\mathrm{HCl} (H 1 + Cl 1).

Dot-and-cross idea (no drawing)

Show electrons from one atom as dots and the other as crosses. A shared pair sits between the symbols of the two atoms. For H2\mathrm{H_2}: one dot and one cross together between the H atoms. For H2O\mathrm{H_2O}: two shared pairs between O and each H, plus two lone pairs on O.

Worked Example

Worked example: Building H2O\mathrm{H_2O}

Properties of simple molecular substances

  • Low melting and boiling points: molecules are held together by weak forces between molecules, even though the covalent bonds inside each molecule are strong.
  • Poor conductors: no free ions or delocalised electrons to carry charge.

Common misconceptions

  • Covalent bonding is sharing, not transferring electrons (that is ionic).
  • The covalent bond inside a molecule is strong; it is the forces between molecules that are weak.
  • Molecules are neutral overall; shared electrons are not “free.”

Tuity Tip

Hover me!

Memory aids

  • 1–2–3–4 rule: H/Cl = 1 bond, O = 2, N = 3, C = 4.
  • Each bond = 2 shared electrons.
  • Count shared + lone electrons to check for 22 (H) or 88 (others).

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