Cambridge (CIE) IGCSE Chemistry

Revision Notes

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(Air Quality and Climate)

Air

Air

Air is the invisible mixture of gases that surrounds Earth. We breathe it, it carries sound, and it helps control Earth’s temperature.

Composition of clean, dry air

  • Nitrogen, N2N_2: about 78%78\%
  • Oxygen, O2O_2: about 21%21\%
  • Remainder (about 1%1\%): noble gases (mainly argon) and carbon dioxide, CO2CO_2 (about 0.04%0.04\%)

Clean, dry means no water vapour. Real air often contains water vapour and tiny particles (dust, smoke).

Air pollutants and their sources

  • Carbon dioxide (CO2CO_2): complete combustion of carbon fuels (e.g. petrol, gas, coal)
  • Carbon monoxide (CO) and particulates: incomplete combustion (poor oxygen supply in engines or stoves)
  • Methane (CH4CH_4): decomposition of vegetation and waste; animal digestion
  • Oxides of nitrogen (NOxNO_x): high-temperature car engines
  • Sulfur dioxide (SO2SO_2): burning sulfur-containing fossil fuels

Adverse effects of pollutants

  • CO2CO_2: higher levels increase global warming, leading to climate change
  • CO: toxic gas (reduces blood’s ability to carry oxygen)
  • Particulates: higher risk of respiratory problems and cancer
  • CH4CH_4: higher levels increase global warming, leading to climate change
  • NOxNO_x: acid rain, photochemical smog, respiratory problems
  • SO2SO_2: acid rain

Greenhouse gases and global warming

Sunlight reaches Earth’s surface and warms it. The warm surface emits thermal (infrared) energy. Greenhouse gases like CO2CO_2 and CH4CH_4 absorb, then emit and partially reflect this thermal energy back towards Earth. This reduces thermal energy lost to space, like a thin blanket. Extra greenhouse gases strengthen this effect, causing global warming and climate change.

Reducing air pollution

  • Burn fewer fossil fuels: use energy efficiently and choose renewables
  • Ensure complete combustion: good ventilation and engine maintenance
  • Car catalytic converters: reduce CO and NOxNO_x
  • Low-sulfur fuels and flue gas desulfurisation: reduce SO2SO_2
  • Capture landfill gas and manage waste: reduce CH4CH_4

Tuity Tip

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Memory aids
  • “78–21–1 rule”: 78%78\% nitrogen, 21%21\% oxygen, ~1%1\% other
  • Engines → NOxNO_x; Sulfur fuels → SO2SO_2; Poor burning → CO + particulates
  • Natural greenhouse effect keeps Earth warm; extra gases cause warming beyond normal

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