Cambridge (CIE) IGCSE Chemistry

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(Hydrogen-Oxygen Fuel Cells)

Hydrogen-Oxygen Fuel Cells

Hydrogen–Oxygen Fuel Cells

A hydrogen–oxygen fuel cell uses hydrogen and oxygen to produce electricity, with water as the only chemical product.

What is a fuel cell?

A fuel cell is like a battery that does not run down while fuel is supplied. It converts the chemical energy of hydrogen and oxygen directly into electrical energy.

How it works (simple view)

  • Anode (−): Hydrogen gas enters and loses electrons. These electrons travel through the external circuit to power a motor or light.
  • Cathode (+): Oxygen gas enters and gains electrons. It reacts with hydrogen ions to form water.
  • Electrolyte: Allows ions to move inside the cell but keeps gases and electrons separate.

In an acidic fuel cell, the half‑equations are:

Anode: H22H++2e\text{Anode: } \mathrm{H_2} \rightarrow 2\mathrm{H^+} + 2\mathrm{e^-}

Cathode: 12O2+2H++2eH2O\text{Cathode: } \tfrac{1}{2}\mathrm{O_2} + 2\mathrm{H^+} + 2\mathrm{e^-} \rightarrow \mathrm{H_2O}

Overall reaction:

2H2+O22H2O2\mathrm{H_2} + \mathrm{O_2} \rightarrow 2\mathrm{H_2O}

Why it matters (uses)

  • Vehicles: cars, buses, and forklifts.
  • Spacecraft: electricity and drinking water on board.
  • Backup power for hospitals and data centres.

Advantages compared with petrol engines

  • Only water is produced at the point of use (no carbon dioxide or nitrogen oxides from the cell itself).
  • Higher efficiency: more of the fuel’s energy becomes electricity.
  • Quiet operation and fewer moving parts.
  • Fast refuelling (minutes), good range.

Disadvantages and challenges

  • Hydrogen storage is difficult (needs high pressure or very low temperature).
  • Hydrogen refuelling stations are limited.
  • Hydrogen production may release carbon dioxide if made from fossil fuels; “green” hydrogen needs renewable electricity.
  • Fuel cells and catalysts (often platinum) are expensive.

Common misconceptions

  • A fuel cell is not a battery: it generates electricity while fuel is supplied; it does not store much energy by itself.
  • The reaction is not a flame; it is an electrochemical process that directly makes electricity.

Tuity Tip

Hover me!

Memory aid: OIL RIG — Oxidation Is Loss (of electrons) at the anode for hydrogen; Reduction Is Gain (of electrons) at the cathode for oxygen. Overall product is water.

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