Cambridge (CIE) IGCSE Chemistry

Revision Notes

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(Solids, Liquids and Gases)

Pressure & Temperature in Gases

Pressure and Temperature in Gases

Gas particles are far apart and move randomly. When they hit the walls of a container, they push on it. This push per unit area is called pressure.

How pressure changes

  • At fixed temperature, squeezing a gas into a smaller volume makes more frequent wall collisions, so pressure rises. Boyle’s law: p1/Vp \propto 1/V.
  • At fixed volume, heating makes faster collisions, so pressure rises. Pressure law: pTp \propto T (T in kelvin).

How temperature changes volume

Heating increases particles’ average kinetic energy. If pressure is kept constant (for example, a loose balloon), the gas expands. Charles’ law: VTV \propto T (T in kelvin; T(K)= ⁣C+273T(\mathrm{K}) = \, ^\circ\!\mathrm{C} + 273).

Everyday links

  • Balloons shrink in a freezer and grow in warm air.
  • Aerosol cans become dangerous if heated: pressure increases in the fixed can volume.
  • Pushing a syringe plunger halves the volume, roughly doubling pressure (if temperature stays the same).

Common misconceptions

  • Heating does not make particles bigger; it makes them move faster.
  • Use kelvin for gas laws, not °C.

Tuity Tip

Hover me!

Tip: Sketch particle diagrams: more collisions (higher p), faster motion (higher T), or more space (higher V).

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