Cambridge (CIE) IGCSE Chemistry
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(Arrangement of Elements)
Periodic Table Trends
Periodic Table Trends
The Periodic Table is arranged by increasing atomic (proton) number. Rows are called periods; columns are called groups. Elements in the same group have similar chemical properties because they have the same number of outer (valence) electrons.
Across a Period (left → right)
- Metallic character decreases; non-metallic character increases.
- Atoms get slightly smaller as the nucleus pulls electrons in more strongly.
- Metals on the left tend to lose electrons (form positive ions like ); non-metals on the right tend to gain or share electrons (form negative ions like ).
Down a Group (top → bottom)
- Atoms get larger (more electron shells). Think of adding more coats—each coat makes the atom bigger.
- Group 1 (alkali metals): reactivity increases down the group; melting point decreases; density generally increases.
- Group 17 (halogens): reactivity decreases down the group; density increases.
Group Number and Ion Charge
- Group 1 forms ions (e.g., ).
- Group 2 forms ions (e.g., ).
- Group 16 forms ions (e.g., ).
- Group 17 forms ions (e.g., ).
Why Elements in a Group Are Similar
They have the same number of outer electrons, so they react in similar ways. For example, Li, Na and K each have 1 outer electron and react with water in similar reactions, but at different speeds.
Group Facts to Know
- Group 1 alkali metals: soft, very reactive; reactivity increases Li → Na → K.
- Group 17 halogens: at room temperature: chlorine is a green gas, bromine is a red-brown liquid, iodine is a dark grey solid (purple vapor when warmed). Reactivity: Cl > Br > I.
Worked Example
Worked example 1: Predict which is more reactive with water: sodium (Na) or rubidium (Rb) from Group 1.
Worked Example
Worked example 2: What ion does sulfur (Group 16) form?
Common Misconceptions
- Period number tells you the number of electron shells, not the charge of the ion.
- Not all metals are highly reactive; position matters (e.g., Group 1 vs. transition metals).
- Halogens exist as diatomic molecules (e.g., , , ).
Tuity Tip
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Memory aids:
- Across a period: metals to non-metals.
- Down Group 1: more reactive; down Group 17: less reactive.
- Group number → typical ion charge sign and size (1 → , 2 → , 16 → , 17 → ).
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