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WAEC WAEC Nigeria Chemistry

Revision Notes
(Hydrogen & Water)

Preparation, properties, fountain experiment

Hydrogen & Water: Preparation, Properties, and Fountain Experiment

Preparation of Hydrogen

Hydrogen is a non-metallic element that is commonly prepared in the laboratory and industry. Let's explore how it's done:

Laboratory Preparation

  • Method: Reacting a dilute acid with a metal such as zinc.
  • Equation: Zn+2HClZnCl2+H2\text{Zn} + 2\text{HCl} \rightarrow \text{ZnCl}_2 + \text{H}_2
  • Apparatus: Conical flask, delivery tube, and a gas jar.
  • Safety: Ensure proper ventilation and avoid open flames.

Industrial Preparation

  • Steam Reforming: Methane reacts with steam at high temperatures.
  • Equation: CH4+H2OCO+3H2\text{CH}_4 + \text{H}_2\text{O} \rightarrow \text{CO} + 3\text{H}_2
  • Water Gas Shift Reaction: Further reaction with steam to increase hydrogen yield.
  • Equation: CO+H2OCO2+H2\text{CO} + \text{H}_2\text{O} \rightarrow \text{CO}_2 + \text{H}_2

Properties of Hydrogen

  • Physical Properties: Colorless, odorless, and tasteless gas.
  • Density: Less dense than air, allowing it to rise.
  • Chemical Properties: Highly flammable, burns with a pale blue flame.
  • Reactivity: Reacts with oxygen to form water: 2H2+O22H2O2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}

Fountain Experiment

The fountain experiment demonstrates the solubility of gases in water:

  • Setup: A round-bottomed flask containing ammonia gas is inverted over a beaker of water.
  • Observation: Water rushes into the flask, creating a fountain effect.
  • Explanation: Ammonia dissolves in water, reducing pressure inside the flask.
PracticeExample 2

Worked Example

Calculate the volume of hydrogen gas produced when 5g of zinc reacts with excess hydrochloric acid.

Safety First: Always conduct experiments in a well-ventilated area and wear safety goggles.

Remember: Hydrogen is lighter than air, so it can easily escape. Ensure all apparatus are sealed properly.

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